过渡金属离子系列

Mn⁴⁺变价专题

1.[Manganese-doped yttrium orthoaluminate: a potential material for holographic recording and data storage-prb-1998] Mn⁴⁺→Mn⁵⁺和Mn³⁺disproportionation reaction

2. ZnSnF₆·6H₂O:Mn⁴⁺
Mn⁴⁺直接变为Mn⁵⁺ and/or disproportionation reaction
[Photo-induced degradation and thermal decomposition in ZnSnF₆·6H₂O:Mn⁴⁺ red-emitting phosphor-OM-2015] 

2. K₂SiF₆:Mn²⁺ 
Xe lamp exposure，或者He–Cd (λ = 325 nm) > Ar+ (488 nm) > He–Ne laser (632.8 nm)都会导致degradation。Mn²⁺直接变为Mn³⁺ and/or disproportionation reaction Mn²⁺→Mn+和Mn³⁺。
[Unique light-induced degradation in yellow-emitting K₂SiF₆:Mn²⁺ phosphor-JAP-2014] 

Mn2+变价光致变色

• Discoloration of Alumina Ceramics with Ultraviolet Radiation and Elucidation of Its Mechanism

 

Bi变价专题

[X‑ray Induced Valence Change and Vacuum Referred Binding Energies of Bi3+ and Bi2+ in Li2BaP2O7—JPCC-2016]

补充-稀土配合物变价

In analogy to Ce(III) (see above), the photooxidations of Ln(II) seem to originate from fd states since the fd transitions terminate at d orbitals which are exposed to the ligands or the solvent. [Excited state properties of lanthanide complexes: Beyond ff states]

 

Photochemistry induced by metal-to-ligand charge transfer excitation