如果在掺杂Eu3+的基质中,用短波长激发,出现了明显的所谓的photo-degradation,那么这大概率是属于长余辉的trapping/OSL detrapping。比如[Unique photoluminescence degradation/recovery phenomena in trivalent ion-activated phosphors]中,用氙灯280 nm照TGG:Eu3+样品1分钟,就有60%以上的强度衰减。
[Development of White Persistent Phosphors by Manipulating Lanthanide Ions in Gadolinium Gallium Garnets]
up/downward charging curve:
downward charging curve:
Tb3+-Eu3+ photo-degradation
在Jonas的[Broadband infrared LEDs based on europium-toterbium charge transfer luminescence]中,存在如下的MMCT(electron hopping)$$ \mathrm{Eu}^{2+} \mathrm{Tb}^{3+} \leftrightarrow \mathrm{Eu}^{3+} \mathrm{Tb}^{2+} $$
在[Sensitizing Eu3+ with Ce3+ and Tb3+ to Make Narrow-Line Red Phosphors for Light Emitting Diodes]中,通过掺入bridge ions Gd3+,实现Ce3+-(Tb3+)n-Eu3+的能量传递,否则的话Ce3+-Eu3+的能量传递会有mutual quenching。
在[Unique photoluminescence degradation/recovery phenomena in trivalent ion-activated phosphors]中,
在[Abnormal photoluminescence phenomena in (Tb3+, Eu3+) codoped Ga2O3 phosphor]
la2wo6 eu3+